Crystal Structure, Cation Occupancy and Vacancy Ordering in Thermoelectric (1-x)SrTiO3-xLa1/3NbO3: A STEM-EELS Study

نویسندگان

  • F. Azough
  • D. M. Kepaptsoglou
  • D. Srivastava
  • Q. M. Ramasse
چکیده

Thermoelectric energy conversion is widely recognized as a promising technology both for electric power generation in terms of waste heat recovery and for cooling of various electronic devices [1]. SrTiO3 based perovskites are among a number of candidate materials for such thermoelectric applications [2]. For the first time, we demonstrate the successful synthesis of (1-x)SrTiO3-xLa1/3NbO3 ceramics that exhibit excellent thermoelectric properties and we have used STEM-EELS in order to assess the quantitative effects of composition on the structure and properties of these materials.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Studying Dynamics of Oxygen Vacancy Ordering in Epitaxial LaCoO3 / SrTiO3 Superlattice with Real-Time Observation

Oxygen vacancies in perovskite oxides are of great interest both from fundamental viewpoint due to their effect on electronic and magnetic properties of oxides – and from applications viewpoint due to their importance for solid oxide fuel cells. In the latter case, understanding the dynamic behavior of vacancies is crucial. Oxygen vacancy (Vo) ordering can substantially affect local structure a...

متن کامل

Correlation Between Oxygen Vacancy, Microstrain, and Cation Distribution in Lithium-Excess Layered Oxides During the First Electrochemical Cycle

Dynamic structural changes during the first electrochemical charge and discharge cycle in the Li-excess layered oxide compound, Li[Li1/5Ni1/5Mn3/5]O2, are studied with synchrotron X-ray diffraction (SXRD), aberration corrected scanning transmission electron microscopy (a-S/TEM), and electron energy loss spectroscopy (EELS). At different states of charge, we carefully examined the crystal struct...

متن کامل

Crystal Structure and Lattice Parameter Investigation of La3+ Substituted CeO2 in LaxCe1-xO2-X/2 Synthesized by Solid-State Method

Lanthanum (La) doped Ceria (CeO2) has attracted considerable interest as a candidate material for thermal barrier coating (TBC) because of its low thermal conductivity and potential capability to be operated above 1250°C. In this study, La2Ce2O7 powder was synthesized through the ball mill method. The crystal structure of La3+ su...

متن کامل

Crystal chemistry of hydrous forsterite and its vibrational properties up to 41 GPa

The crystal structure of hydrous pure magnesium forsterite (Mg2SiO4) containing 8900 ppmw H2O, synthesized at 12 GPa and 1250 °C, has been refined. The major hydration mechanism appears to be M1 cation vacancy with protonation of the O1-O2 octahedral edge of M1. Raman spectra up to 41 GPa show strong coupling between the two Ag modes (824.4 and 856.2 cm–1). Mode Grüneisen parameters γi related ...

متن کامل

Synthesis, Characterization, and Crystal Structure Determination of a New Copper(II) Complex: [H2en][Cu(pydc)2].2H2O

The new complex of [H2en][Cu(pydc)2].2H2O (1) (where H2en and pydc are ethylenediammonium and 2,6-pyridinedicarboxylate, respectively) was synthesized by the reaction of a mixture of ethylenediamine (en) and 2,6-pyridinedicarboxylic acid (H2pydc) in a mixture of CH3OH/H2O as solvent. This complex was fully characterized by elemental analysis, IR, UV–Vis spectroscopy as well as single-crystal X-...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2014